Phospholide
WebJul 26, 1994 · Several aspects of the chemistry of phospholide and polyphospholide ions under current development are described briefly. They include: the synthesis of flexible tetraphosphorus macrocycles from 2,2′-biphospholide ions; the synthesis of functional phospholide, 1,3- arsaphospholide and 1,2,3-triphospholide ions; the description of new … WebApr 17, 2024 · The 1,2-diaza-4-phospholide (dp −) dipotassium ate complexes of chromium(II) {[(η 1-N-3,5-tBu 2 dp) 4 Cr][(η 5-(N,N,C,C,P)) 2-K(η 1-O-THF) 2] 2} (5) and {[(η 1-N-3,5-Ph 2 dp) 4 Cr][(η 5-(N,N,C,C,P)) 2-K(η 1-O-THF) 2] 2} ∞ (6) were synthesized and characterized by X-ray single crystal structure analysis.Complex 5 with a near-square …
Phospholide
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WebSep 30, 2012 · In this paper we describe the synthesis and spectroscopic characterisation of the products from the reaction of ruthenium and osmium carbonyl clusters with 3,4 … WebA novel reaction mode of phosphametallocenes was discovered. The phospharuthenocenes with cyclohexyl substituents at the α-positions of the η5-phospholide(s) reacted with acyl electrophiles by an initial electrophilic attack to the ruthenium to produce the μ-alkenylidene species with activation of the acyl C═O double bond and elimination of an α-hydrogen.
WebMar 1, 2006 · This review covers recent achievements in the area of low coordinate phosphorus ligands featuring P C double bonds such as phosphaalkenes, phospholide … WebDec 1, 1994 · The aromatic anions phospholide and arsolide have been generated in the gas phase at room temperature via the reaction of hydroxide ion with 1-tert-butylphosphole …
WebNov 10, 2010 · ChemInform Abstract: Simple Access to α-Functional Phospholide Ions. Part 2. Application to the Synthesis of 1Methyl2-pyrrolyl and 2- (Diphenylphosphino)phenyl Derivatives Authors: S. HOLAND N.... WebDec 1, 2001 · Synthesis of Phosphole-2,5-dicarboxylic Acids via a [1,5]-Shift of Carbon Dioxide Around the Phosphole Nucleus Article Full-text available May 2002 Mohand Melaimi Louis Ricard François Mathey...
WebOct 28, 2024 · Here we show that a per-alkylated phospholide, TMP (TMP = {PC 4 Me 4 }) allows the one-pot synthesis and isolation of trivalent dibenzyl-ate complexes of the form [M (TMP) 2 { (μ:η 1 :η 6 -C 7 H 7) 2 K (η 6 -arene)}] (arene = toluene or benzene) of U, Np, and Pu, along with isoradial lanthanide congeners La, Ce, and Pr.
WebSep 1, 2012 · The reaction of [Ru3 (CO)12] with 3,4-dimethyl-1-phenylphosphole under mild conditions affords three derivatives which were identified by means of spectroscopic methods as the substitution... sharmane andersonWebphospholide anion. Formula: C 4 H 4 P-Molecular weight: 83.0489; Information on this page: Reaction thermochemistry data; References; Notes; Other data available: Gas phase ion energetics data; Options: Switch to calorie-based units sharman core testWebSelect search scope, currently: articles+ all catalog, articles, website, & more in one search; catalog books, media & more in the Stanford Libraries' collections; articles+ journal articles & other e-resources sharman d neill jewelleryWebPhospholes are an important class of five-membered unsaturated phosphorus heterocycles. The substantial enhancement of phosphole chemistry in the last few decades is mainly due to their numerous applications in organic electronics, catalysis and other … population of knightdale ncWebDec 31, 1994 · The aromatic anions phospholide and arsolide have been generated in the gas phase at room temperature via the reaction of hydroxide ion with 1-tert … population of knox countyWebApr 6, 2024 · Chemical properties of phospholide anions 558 Major tendencies in modern chemistry of alkali and transition metal phospholides (phosphacyclopentadienides) are … population of klamath falls orWebA process to produce 1-octene and 1-decene includes (a) separating a composition containing an oligomer product – which contains from 15 to 80 mol % C6 olefins, from 20 to 80 mol % C8 olefins, and from 5 to 20 mol % C10+ olefins – into a first oligomer composition containing C6 alkanes and at least 85 mol % C6 olefins (e.g., 1-hexene), a second … population of klein texas